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Question: Answered & Verified by Expert
In the first order reaction, the concentration of the reactants is reduced to \( 25 \% \) in one hour. The half-life period of the reaction is
ChemistryChemical KineticsJEE Main
Options:
  • A \( 2 \mathrm{~h} \)
  • B \( 4 \mathrm{~h} \)
  • C \( 1 / 2 \mathrm{~h} \)
  • D \( 1 / 4 \mathrm{~h} \)
Solution:
1500 Upvotes Verified Answer
The correct answer is: \( 1 / 2 \mathrm{~h} \)

For first order reaction,
k=2.303t1/2logaa-a2=2.303tloga(a-x)
2.303t1/2log2=2.3031logaa/4
2.303×0.3010t1/2=2.303×log4
t1/2=0.3010log4=0.30100.6020=12h

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