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Question: Answered & Verified by Expert
In the Gattermann reaction, a diazonium group is replaced by \( \mathrm{X} \) using \( \mathrm{Y} ; \mathrm{X} \) and \( \mathrm{Y} \) are
ChemistryAminesJEE Main
Options:
  • A \(\mathrm{X} \text{ and } \mathrm{Y} =\mathrm{Cl}^{-} \quad =\mathrm{Cu} / \mathrm{HCl} \)
  • B \(\mathrm{X} \text{ and } \mathrm{Y} =\mathrm{Cl}^{+} \quad \mathrm{Y}=\mathrm{CuCl}_{2} / \mathrm{HCl} \)
  • C \(\mathrm{X} \text{ and } \mathrm{Y} =\mathrm{Cl}^{-} \quad \mathrm{Y}=\mathrm{CuCl}_{2} / \mathrm{HCl} \)
  • D \(\mathrm{X} \text{ and } \mathrm{Y} =\mathrm{Cl}_{2} \mathrm{Y}=\mathrm{Cu}_{2} \mathrm{O} / \mathrm{HCl} \)
Solution:
2500 Upvotes Verified Answer
The correct answer is: \(\mathrm{X} \text{ and } \mathrm{Y} =\mathrm{Cl}^{-} \quad =\mathrm{Cu} / \mathrm{HCl} \)

When the benzene diazonium salt reacts with the halogen in the presence of copper powder, then it is known as the Gatterman reaction.

ArN2+Cl- + HCl Cu ArCl + N2 + CuCl

So, X-Cl- & Y=Cu/HCl.

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