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In the neutral or faintly alkaline medium, KMnO4 oxidises iodide into iodate. The change in oxidation state of manganese in this reaction is from
Chemistryd and f Block ElementsNEETNEET 2022 (Phase 1)
Options:
  • A +6 to +4
  • B +7 to +3
  • C +6 to +5
  • D +7 to +4
Solution:
2076 Upvotes Verified Answer
The correct answer is: +7 to +4

KMnO4 acts as an oxidising agent. In neutral or faintly alkaline medium When alkaline KMnO4 is treated with KI, iodide ion is oxidised to iodate IO3- andKMnO4 is reduced to MnO2.  The chemical reaction can be given as,

2KMnO4+H2O+KI2MnO2+2KOH+KIO3

The change in oxidation state of manganese in this reaction is from +7 to +4.

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