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Question: Answered & Verified by Expert
In the preparation of chlorine by the electrolysis of brine, the reaction taking place at the anode is
ChemistrySurface ChemistryTS EAMCETTS EAMCET 2019 (03 May Shift 2)
Options:
  • A Cl- aq12Cl2 ( g)+e-
  • B Na+ aq+e-Na (s)
  • C O2 (g)+4H++4e-4H2O (l)
  • D H+ aq+e-1/2H2 (g)
Solution:
2442 Upvotes Verified Answer
The correct answer is: Cl- aq12Cl2 ( g)+e-

Brine is a solution of sodium chloride and water. The electrolysis of brine is a large-scale process used to manufacture chlorine from salt.

 At anode, chloride (Cl-) ions are oxidised by electron loss to form chlorine gas. This is an oxidation reaction because the chloride ions lose electrons.

Cl- aq12Cl2 ( g)+e-

The net process is the electrolysis of an aqueous solution of NaCl into industrially useful products sodium hydroxide (NaOH) and chlorine gas. 

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