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Question: Answered & Verified by Expert
In two separate experiments equal quantities of an alkyl halide, C4H9Cl , were treated at the same temperature with equal volume of 0.1 molar and 0.2 molar solutions of NaOH respectively. In the two experiments, t1/2 of the two reactions were the same. The most likely structure of halide is
ChemistryHaloalkanes and HaloarenesNEET
Options:
  • A CH3CH2CH2CH2Cl
  • B CH3CH(Cl)CH2CH3
  • C (CH3)2CHCH2Cl
  • D (CH3)3CCl
Solution:
1255 Upvotes Verified Answer
The correct answer is: (CH3)3CCl
As it is independent of the concentration of NaOH. So, it undergoes via SN1 . So, most likely the halide is tertiary halide. So option D is correct.

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