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Question: Answered & Verified by Expert
In which of the following arrangements, the sequence is not strictly according to the property written against it?
ChemistryClassification of Elements and Periodicity in PropertiesJEE MainJEE Main 2012 (07 May Online)
Options:
  • A
    $\mathrm{CO}_2 < \mathrm{SiO}_2 < \mathrm{SnO}_2 < \mathrm{PbO}_2$ : increasing oxidising power
  • B
    $\mathrm{NH}_3 < \mathrm{PH}_3 < \mathrm{AsH}_3 < \mathrm{SbH}_3$ : increasing basic strength
  • C
    $\mathrm{HF} < \mathrm{HCl} < \mathrm{HBr} < \mathrm{HI}$ : increasing acid strength
  • D
    $\mathrm{B} < \mathrm{C} < \mathrm{O} < \mathrm{N}$ : increasing first ionisation enthalpy.
Solution:
2415 Upvotes Verified Answer
The correct answer is:
$\mathrm{NH}_3 < \mathrm{PH}_3 < \mathrm{AsH}_3 < \mathrm{SbH}_3$ : increasing basic strength
Correct order of increasing basic strength is $\mathrm{NH}_3>\mathrm{PH}_3>\mathrm{AsH}_3>\mathrm{SbH}_3>\mathrm{BiH}_3$

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