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Question: Answered & Verified by Expert
In which of the following molecules all A-X bond lengths are identical?
[A = central atom and X = surrounding atom]
ChemistryChemical Bonding and Molecular StructureNEET
Options:
  • A XeF4
  • B PF5
  • C Both A and B
  • D SF4
Solution:
1313 Upvotes Verified Answer
The correct answer is: XeF4

Hybridisation of Xe sp3d2
All four Xe-F bonds are of equal lengths as they lie in the same plane and are at 90° apart from each other.

Hybridisation sp3d
(P-F)axial>(1.58Å)(P-F)equatorial(1.53Å)

Hybridisation sp3d
(S-F)axial>(S-F)equatorial

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