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Question: Answered & Verified by Expert
Increasing rate of SN1 reaction in the following compounds is:
(I)
(II)
(III)
(IV)
ChemistryHaloalkanes and HaloarenesJEE MainJEE Main 2019 (10 Apr Shift 1)
Options:
  • A (I)<(II)< (III)<(IV)
  • B (II)<(I)< (III)<(IV)
  • C (II)<(I)< (IV)<(III)
  • D (I)<(II)< (IV)<(III)
Solution:
1889 Upvotes Verified Answer
The correct answer is: (II)<(I)< (III)<(IV)

The rate of SN1 reaction stability of carbocation
stability of carbocation +ve charge delocation.
+M,+HC,+I
Order of effect effectiveness
+M>+HC>+I (+M )> (-I)


So, order of stability B<A<C<D

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