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Question: Answered & Verified by Expert
Indicate the products $(\mathrm{X})$ and $(\mathrm{Y})$ in the following reactions:
$\begin{array}{lr}
\mathrm{Na}_{2} \mathrm{~S}+\mathrm{nS}(\mathrm{n}=1-8) & \rightarrow(\mathrm{X}) \\
\mathrm{Na}_{2} \mathrm{SO}_{3}+\mathrm{S} & \rightarrow(\mathrm{Y})
\end{array}$
$\begin{array}{ll}(\mathrm{X}) & (\mathrm{Y})\end{array}$
ChemistryRedox ReactionsWBJEEWBJEE 2021
Options:
  • A $\mathrm{Na}_{2} \mathrm{~S}_{2} \mathrm{O}_{3} \quad \mathrm{Na}_{2} \mathrm{~S}_{2}$
  • B $\mathrm{Na}_{2} \mathrm{~S}_{(n+1)} \quad \mathrm{Na}_{2} \mathrm{~S}_{2} \mathrm{O}_{3}$
  • C $\mathrm{Na}_{2} \mathrm{~S}_{\mathrm{n}} \quad \mathrm{Na}_{2} \mathrm{~S}_{2} \mathrm{O}_{3}$
  • D $\mathrm{Na}_{2} \mathrm{~S}_{5} \quad \mathrm{Na}_{2} \mathrm{~S}_{2} \mathrm{O}_{4}$
Solution:
1790 Upvotes Verified Answer
The correct answer is: $\mathrm{Na}_{2} \mathrm{~S}_{(n+1)} \quad \mathrm{Na}_{2} \mathrm{~S}_{2} \mathrm{O}_{3}$
$\begin{array}{l}
\mathrm{Na}_{2} \mathrm{~S}+\mathrm{nS} \longrightarrow \mathrm{Na}_{2} \mathrm{~S}_{(\mathrm{n}+1)} \\
\mathrm{Na}_{2} \mathrm{SO}_{3}+\mathrm{S} \longrightarrow \mathrm{Na}_{2} \mathrm{~S}_{2} \mathrm{O}_{3}
\end{array}$

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