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Question: Answered & Verified by Expert
Iodine oxidises sodium borohydride to give
Chemistryp Block Elements (Group 15, 16, 17 & 18)AIIMSAIIMS 2011
Options:
  • A $\mathrm{B}_2 \mathrm{H}_6$
  • B sodium hydride
  • C $\mathrm{HI}$
  • D $\mathrm{I}_3^{-}$
Solution:
2646 Upvotes Verified Answer
The correct answer is: $\mathrm{B}_2 \mathrm{H}_6$
The oxidation of sodium borohydride with iodine in diglyme gives diborane.
$$
2 \mathrm{NaBH}_4+\mathrm{I}_2 \stackrel{\text { Diglyme }}{\longrightarrow} \mathrm{B}_2 \mathrm{H}_6+2 \mathrm{NaI}+\mathrm{H}_2
$$

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