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Question: Answered & Verified by Expert
$\mathrm{KMnO}_4$ in alkaline medium changes to
Chemistryd and f Block ElementsAIIMSAIIMS 2014
Options:
  • A $\mathrm{Mn}^{3+}$
  • B $\mathrm{MnO}_2$
  • C $\mathrm{MnO}_4^{2-}$
  • D $\operatorname{Mn}(\mathrm{OH})_4^{-}$
Solution:
1035 Upvotes Verified Answer
The correct answer is: $\mathrm{MnO}_2$
In alkaline solution, $\mathrm{KMnO}_4$ is first reduced to manganate and then to insoluble manganese dioxide.
$\begin{aligned}
& 2 \mathrm{KMnO}_4+\mathrm{H}_2 \mathrm{O} \stackrel{\text { alkaline }}{\longrightarrow} 2 \mathrm{MnO}_2+2 \mathrm{KOH} \\
&+3[\mathrm{O}]
\end{aligned}$

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