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Match List I with List II:
| List I (Complexes) | List II (Hybridisation) | ||
| (A) | I | ||
| (B) | II | ||
| (C) | III | ||
| (D) | IV | ||
is in zero oxidation state in . So, the electronic configuration of is . As is a strong ligand, it pushes all the electrons in the 3d orbital, therefore the hybridisation of is sp3 and it has tetrahedral geometry. It is diamagnetic due to the absence of unpaired electrons.
ion, oxidation state of is +2 and its valence shell electronic configuration is . So, there would be a rearrangement of electrons in because of the strong field ligand . And the last electron in the d-orbital would be out waiting for the N's electrons to fill up first. So, the 4 electron pairs from would be in one 3d, one 4s, & two 4p orbitals and in the third place of 4p orbital, the e- from 3d would take place. So, you can say the hybridisation here would be .
ion, oxidation state of is +2 and its valence shell electronic configuration is . is strong field ligand with complex. So, no pairing will be there. So, you can say the hybridisation here would be .
ion, oxidation state of is +2 and its valence shell electronic configuration is . There are 4 unpaired electrons in 3d orbital. So, you can say the hybridisation here would be .
So, correct order of matching is given in the below table:
| List I (Complexes) | List II (Hybridisation) |
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