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Match List I with List II.

  List-I
(Anion)
  List-II
(gas evolved on reaction with dil. H2SO4)
(A) CO32- (I)

Colourless gas which turns lead acetate paper black.

(B) S2- (II)

Colourless gas which turns acidified potassium dichromate solution green.

(C) SO32- (III) Brown fumes which turns acidified KI solution containing starch blue.
(D) NO2- (IV) Colourless gas evolved with brisk effervescence, which turns lime water milky.

Choose the correct answer from the options given below

ChemistryPractical ChemistryJEE MainJEE Main 2022 (27 Jun Shift 2)
Options:
  • A A-III,B-I,C-II,D-IV
  • B A-II,B-I,C-IV,D-III
  • C A-IV,B-I,C-III,D-II
  • D A-IV,B-I,C-II,D-III
Solution:
2410 Upvotes Verified Answer
The correct answer is: A-IV,B-I,C-II,D-III

When small amount of carbonate salt is treated with dilute H2SO4 or dilute HCl, A colourless, odourless gas CO2 is evolved with brisk effervescence

When small amount of the following salts are treated with dilute H2SO4  the following observations are seen.

Carbonate salt CO32 Brisk effervescence of CO2 gas, CO32+H2SO4SO42+H2O+CO2
Sulphide salt S-2 A colourless gas H2S with rotten egg smell

Na2S+H2SO4Na2SO4+H2S

NO2 –  on reaction with dilute H2SOwill give brown NO2(g) will turn KI solution blue.

SO32-on reaction with dilute H2SO4 will give SO2g, which will turn acidified potassium dichromate solution green.

 

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