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Match List-I with List-II.

1-Bromopropane is reacted with reagents in List-I to give product in List-II

  List-I Reagent   List-II Product
A. KOH (alc) I. Nitrile
B. KCN (alc) II. Ester
C. AgNO2 III. Alkene
D H3CCOOAg IV. Nitroalkane
Choose the correct answer from the options given below

 

ChemistryHaloalkanes and HaloarenesJEE MainJEE Main 2023 (13 Apr Shift 2)
Options:
  • A A-III, B-I, C-IV, D-II
  • B A-I, B-II, C-III, D-IV
  • C A-I, B-III, C-IV, D-II
  • D A-IV, B-III, C-II, D-I
Solution:
2331 Upvotes Verified Answer
The correct answer is: A-III, B-I, C-IV, D-II

(A) When 1-bromopropane reacts with alcoholic KOH, the bromine with the alpha H (hydrogen from the carbon alongside the carbon fortified with useful gathering) is eliminated and subsequently forms 1-propene. 

(B) When 1-Bromo propane reacts with alc KCN it will form butanenitrile. 

(C)  When akyl halide reacts with silver nitrite, nitroalkane is formed because the bond between AgOAgO is covalent, the lone pair on nitrogen acts as an attacking site for nucleophilic substitution.  

(D) When 1-bromopropane reacts with silver acetate, propyl ethanoate and silver bromide are formed.

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