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Question: Answered & Verified by Expert

Match List-I with List-II.

  List-I   List-II
A

I Gatterman Koch reaction
B

II Etard reaction
C

III Stephen reaction
D

IV Rosenmund reaction

Choose the correct answer from the options given below

ChemistryAldehydes and KetonesJEE MainJEE Main 2022 (27 Jul Shift 2)
Options:
  • A A-IV,B-III,C-II,D-I
  • B A-I,B-II,C-III,D-IV
  • C A-II,B-III,C-IV,D-I
  • D A-III,B-II,C-I,D-IV
Solution:
1192 Upvotes Verified Answer
The correct answer is: A-IV,B-III,C-II,D-I

Benzoyl chloride is hydrogenated over catalyst, palladium on barium sulphate. This reaction is called Rosenmund reduction.

 

Nitriles are reduced to corresponding imine with stannous chloride in the presence of hydrochloric acid, which on hydrolysis give corresponding aldehyde.

This is named as Stephen reaction

Use of  Chromyl chloride oxidises methyl group to a chromium complex, which on hydrolysis gives corresponding benzaldehyde.This is called etard reaction

 

 

When benzene or its derivative is treated with carbon monoxide and hydrogen chloride in the presence of anhydrous aluminium chloride or cuprous chloride, it gives benzaldehyde or substituted benzaldehyde.

This is called Gattermann-koch reaction.The mechanism of this reaction is electrophilic substitution.

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