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Match List-I with List-II :
$\begin{array}{|l|l|}
\hline \text{List-I } & \text{List-II } \\
\text{(Reaction) } & \text{(Product formed) } \\
\hline \text{(a) Gabriel synthesis} & \text{(i) Benzaldehyde} \\
\text{(b) Kolbe synthesis} & \text{(ii) Ethers} \\
\text{(c) Williamson synthesis} & \text{(iii) Primary amines} \\
\text{(d) Etard synthesis} & \text{(iv) Salicyclic acid} \\
\hline
\end{array}$
Choose the correct answer from the options given below :
Options:
$\begin{array}{|l|l|}
\hline \text{List-I } & \text{List-II } \\
\text{(Reaction) } & \text{(Product formed) } \\
\hline \text{(a) Gabriel synthesis} & \text{(i) Benzaldehyde} \\
\text{(b) Kolbe synthesis} & \text{(ii) Ethers} \\
\text{(c) Williamson synthesis} & \text{(iii) Primary amines} \\
\text{(d) Etard synthesis} & \text{(iv) Salicyclic acid} \\
\hline
\end{array}$
Choose the correct answer from the options given below :
Solution:
2066 Upvotes
Verified Answer
The correct answer is:
(a) - (iii), (b) - (iv), (c) - (ii), (d) - (i)
(a) Gabriel synthesis $\longrightarrow$ (iii) Primary amines
Pthalimide is alkylated with primary or unbranched secondary alkyl halides or sulphonate. The product thus obtained is hydrolysed to give primary amines.
Treatment of toluene with chromyl chloride in an inert solvent like $\mathrm{CS}_2$ or $\mathrm{CCl}_4$ forms an insoluble complex $\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}\left(\mathrm{OCrCl}_2 \mathrm{OH}\right)_2$ which further on hydrolysis produces benzaldehyde.
Pthalimide is alkylated with primary or unbranched secondary alkyl halides or sulphonate. The product thus obtained is hydrolysed to give primary amines.
Treatment of toluene with chromyl chloride in an inert solvent like $\mathrm{CS}_2$ or $\mathrm{CCl}_4$ forms an insoluble complex $\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}\left(\mathrm{OCrCl}_2 \mathrm{OH}\right)_2$ which further on hydrolysis produces benzaldehyde.
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