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Question: Answered & Verified by Expert
\( \mathrm{A} \rightarrow \mathrm{A}^{-}+\mathrm{e}, \mathrm{E}_{1} \) and \( \mathrm{A}^{+} \rightarrow \mathrm{A}^{2+}+\mathrm{e}, \mathrm{E}_{2} \). The energy required to pull out the two electrons are \( \mathrm{E}_{1} \) and \( \mathrm{E}_{2} \) respectively. The correct relationship between two energy would be :
ChemistryClassification of Elements and Periodicity in PropertiesJEE Main
Options:
  • A \( \mathrm{E}_{1} < \mathrm{E}_{2} \)
  • B \( \mathrm{E}_{1}>\mathrm{E}_{2} \)
  • C \( \mathrm{E}_{1}=\mathrm{E}_{2} \)
  • D \( \mathrm{E}_{1} \neq \mathrm{E}_{2} \)
Solution:
2119 Upvotes Verified Answer
The correct answer is: \( \mathrm{E}_{1} < \mathrm{E}_{2} \)

The second ionization energy is always higher than the first ionization energy as an electron is to be removed from unipositive cation. There is a strong electrostatic attractive force between the unipositive cation and the electron. This makes the removal of electron difficult and requires a large amount of energy.

Always IP2>IP1
So E2>E1

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