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\( \mathrm{RNH}_{2} \) reacts with \( \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{SO}_{2} \mathrm{Cl} \) in aqueous \( \mathrm{KOH} \) to give a clear solution. On acidification, a precipitate is obtained which is due to the formation of
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Benezene sulphonyl chloride is known as Hinsberg reagent and in presence of this reagent primary amines form precipitate.
N-alkyl benzene sulphonamide is formed as precipitate.
Tertiary amines do not react with hinsberg reagent and do not give hinsberg test.
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