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Question: Answered & Verified by Expert
Mixture containing aqueous Li+, Na+, K+ ions are electrolysed. cations are discharged at cathode in the order : (easiest at the end)

M + aq + e - M
ChemistryClassification of Elements and Periodicity in PropertiesNEET
Options:
  • A Li + Na + K +
  • B K + Na + Li +
  • C Li + K + Na +
  • D Na + K + Li +
Solution:
1785 Upvotes Verified Answer
The correct answer is: Na + K + Li +
E red o Metal
-3.05V Li
-2.71V Na
-2.93V K

Higher the value of E red o more preferably the ions is reduced at cathode that is Na+ > K+ > Li+

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