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Question: Answered & Verified by Expert
Mixture of 1 g each of Na2CO3 and NaHCO3 is reacted with 0.1 N HCl. The quantity of 0.1 M HCl required to react completely with the above mixture is
ChemistrySome Basic Concepts of ChemistryJEE Main
Options:
  • A 15.78 mL
  • B 157.8 mL
  • C 198.4 mL
  • D 308 mL
Solution:
1091 Upvotes Verified Answer
The correct answer is: 308 mL
Na 2 CO 3 + 2 HCl 2 NaCl + H 2 O + CO 2 1 mol 2 mol

Na 2 CO 3 = 1 g= 1 106 mol.N a 2 C o 3 2 106 mol.HCl

NaHCO 3 + HCl NaCl + H 2 O + CO 2

NaHCO 3 = 1 g = 1 8 4 mol 1 8 4 mol HCl

Total HCl required = 1 5 3 + 1 8 4 mol HCl

Let volume of 0.1 N HCl = V mL

then, Moles 0.1 × V 1 0 0 0 = V 1 0 0 0 0

∴   V 1 0 0 00 = 1 5 3 + 1 8 4

            0.0308 mol

V = 0.0308 × 1 0 0 0 0

   308 mL

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