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Question: Answered & Verified by Expert
One mole of P4 reacts with 8 moles of SOCl2 to give 4 moles of Ax mole of SO2 and 2 moles of BA, B and x respectively are
Chemistryp Block Elements (Group 15, 16, 17 & 18)JEE MainJEE Main 2023 (11 Apr Shift 2)
Options:
  • A POCl3, S2Cl2 and 2
  • B PCl3, S2Cl2 and 4
  • C PCl3, S2Cl2 and 2
  • D POCl3, S2Cl2 and 4
Solution:
2294 Upvotes Verified Answer
The correct answer is: PCl3, S2Cl2 and 4

Thionyl chloride reacts with white phosphorus to produce phosphorus trichloride. The other side products in this reaction are sulphur dioxide and Sulphur monochloride.

P4+8SOCl24PCl3+4SO2+2S2Cl2 
        Hence A=PCl3, x=4, B=S2Cl2

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