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Question: Answered & Verified by Expert
Optical activity of an enantiomeric mixture is +12.6° and the specific rotation of + isomer is +30°. The optical purity is____%
ChemistryBiomoleculesJEE MainJEE Main 2022 (27 Jul Shift 1)
Solution:
2061 Upvotes Verified Answer
The correct answer is: 42

The "optical purity" is a comparison of the optical rotation of a pure sample of unknown stereochemistry versus the optical rotation of a sample of pure enantiomer. It is expressed as a percentage. If the sample only rotates plane-polarized light half as much as expected, the optical purity is 50%.

% optical purity =observed rotation of mixture×100rotation of pure enantiomer

=+12.6°+30°×100=42

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