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Question: Answered & Verified by Expert
Percentage of free space in a body centre cubic unit cell is
ChemistrySolid StateJIPMERJIPMER 2014
Options:
  • A $30 \%$
  • B $32 \%$
  • C $34 \%$
  • D $28 \%$
Solution:
2112 Upvotes Verified Answer
The correct answer is: $32 \%$
Packing fraction
$=\frac{\text { Volume occupied by atoms in a unit cell }}{\text { Volume of the unit cell }}$
For body centred cube,
Packing fraction $=\frac{2 \times \frac{4}{3} \pi r^3}{\left(\frac{4 r}{\sqrt{3}}\right)^3}=\frac{\sqrt{3} \pi}{8}=0.68$
$\therefore \quad$ Volume occupied $=68 \%$
and volume vacant $=32 \%$

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