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Question: Answered & Verified by Expert
Reactivity order of halides for dehydrohalogenation is:
ChemistryHaloalkanes and HaloarenesNEETNEET 2002
Options:
  • A R-F $>$ R-Cl $>$ R-Br $>$ R-I
  • B R-I $>$ R-Br $>$ R-Cl $>$ R-F
  • C R-I $>$ R-Cl $>$ R-Br $>$ R-F
  • D R-F $>$ R-I $>$ R- $\mathrm{Br}>$ R-Cl
Solution:
1944 Upvotes Verified Answer
The correct answer is: R-I $>$ R-Br $>$ R-Cl $>$ R-F
The alkyl halides are very reactive due to highly polarized $\mathrm{R}-\mathrm{X}$ bonds with a large difference in electronegativities of carbon and halogen atoms. Thus, reactivity of $\mathrm{R}-\mathrm{X}$ depends on bond length.More be the bond length, easier for the $\mathrm{R}-\mathrm{X}$ to go for dehydrohalogenation.
Related Theory
Halogens increase in reactivity from the bottom to the top of their Group.

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