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Question: Answered & Verified by Expert
Reversible expansion of an ideal gas under isothermal and adiabatic conditions are as shown in the figure.


$A B \rightarrow$ Isothermal expansion
$A C \rightarrow$ Adiabatic expansion
Which of the following option is not correct?
ChemistryThermodynamics (C)NEETNEET 2019 (Odisha)
Options:
  • A $\Delta S_{\text {isothermal }}>\Delta S_{\text {adiabatic }}$
  • B $T_A=T_B$
  • C $W_{\text {isothermal }}>W_{\text {adiabatic }}$
  • D $T_c>T_A$
Solution:
2337 Upvotes Verified Answer
The correct answer is: $T_c>T_A$
From first law of thermodynamics,
$$
\Delta \mathrm{U}=\mathrm{q}+\mathrm{W}
$$
In adiabatic expansion, $q=0$
$$
\therefore \quad \Delta \mathrm{U}=\mathrm{W}
$$
During expansion of a gas $w$ is negative i.e $w < 0$ or $\Delta \mathrm{U} < 0$.
We know that, $\Delta \mathrm{U}=\mathrm{nC}_{\mathrm{V}} \Delta \mathrm{T}$
$$
\begin{array}{lclc}
\therefore & \mathrm{nC}_{\mathrm{V}} \Delta \mathrm{T} < 0 & \text { or } & \Delta \mathrm{T} < 0 \\
\therefore & \mathrm{T}_{\mathrm{C}}-\mathrm{T}_{\mathrm{A}} < 0 & \text { or } & \mathrm{T}_{\mathrm{C}} < \mathrm{T}_{\mathrm{A}}
\end{array}
$$
Thus, option (4) is incorrect while the remaining options are correct.

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