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Roasted copper pyrite on smelting with sand produces
ChemistryGeneral Principles and Processes of Isolation of MetalsWBJEEWBJEE 2015
Options:
  • A $\mathrm{FeSiO}_{3}$ as fusible slag and $\mathrm{Cu}_{2} \mathrm{S}$ as matte
  • B $\mathrm{CaSiO}_{3}$ as infusible slag and $\mathrm{Cu}_{2} \mathrm{O}$ as matte
  • C $\mathrm{Ca}_{3}\left(\mathrm{PO}_{4}\right)_{2}$ as fusible slag and $\mathrm{Cu}_{2} \mathrm{S}$ as matte
  • D $\mathrm{Fe}_{3}\left(\mathrm{PO}_{4}\right)_{2}$ as infusible slag and $\mathrm{Cu}_{2} \mathrm{S}$ as matte
Solution:
2709 Upvotes Verified Answer
The correct answer is: $\mathrm{FeSiO}_{3}$ as fusible slag and $\mathrm{Cu}_{2} \mathrm{S}$ as matte
Roasted copper pyrite on smelting with sand produces $\mathrm{FeSiO}_{3}$ as fusible slag and $\mathrm{Cu}_{2}$ S as matte
For removing the gangue, FeS, silica present in the lining of the Bessemer converter, acts as a flux and forms slag (iron silicate) on reaction with FeO.
$\mathrm{FeS}+3 \mathrm{O}_{2} \longrightarrow 2 \mathrm{FeO}+2 \mathrm{SO}_{2}$
$\mathrm{FeO}+\mathrm{SiO}_{2} \longrightarrow \mathrm{FeSiO}_{3}$
Copper matte mainly contains $\mathrm{Cu}_{2} \mathrm{S}$ and FeS.

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