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Question: Answered & Verified by Expert
The correct order of increasing bond angles in the following species is
ChemistryChemical Bonding and Molecular StructureNEETNEET 2010 (Screening)
Options:
  • A $\mathrm{Cl}_2 \mathrm{O} < \mathrm{ClO}_2 < \mathrm{ClO}_2^{-}$
  • B $\mathrm{ClO}_2 < \mathrm{Cl}_2 \mathrm{O} < \mathrm{ClO}_2^{-}$
  • C $\mathrm{Cl}_2 \mathrm{O} < \mathrm{ClO}_2^{-} < \mathrm{ClO}_2$
  • D $\mathrm{ClO}_2^{-} < \mathrm{Cl}_2 \mathrm{O} < \mathrm{ClO}_2$
Solution:
2310 Upvotes Verified Answer
The correct answer is: $\mathrm{ClO}_2^{-} < \mathrm{Cl}_2 \mathrm{O} < \mathrm{ClO}_2$
Key Idea As the number of lone pairs of electrons increases, bond angle decreases due to repulsion between lp-lp. Moreover, as the electronegativity of central atom decreases, bond angle decreases.
Hence, the order of bond angle is


( $\mathrm{Cl}$ is less electronegative as compared to $\mathrm{O}$.)

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