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Question: Answered & Verified by Expert
The following reaction method


is not suitable for the preparation of the corresponding haloarene products, due to high reactivity of halogen, when X is :
ChemistryHaloalkanes and HaloarenesNEETNEET 2024 (Re-NEET)
Options:
  • A F
  • B I
  • C Cl
  • D Br
Solution:
2058 Upvotes Verified Answer
The correct answer is: F
- Aryl chlorides and bromides can easily be prepared by electrophilic substitution of arenes (toluene) with $\mathrm{Cl}_2$ and $\mathrm{Br}_2$ respectively in the presence of Lewis acid catalyst ( Fe in dark).
- Reaction with $\mathrm{I}_2$ is reversible and requires the presence of oxidising agent.
- Corresponding fluoroarene is not prepared by this method due to high reactivity of fluorine. Hence, ' X ' is $F$.

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