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Question: Answered & Verified by Expert
The formation of cyanohydrin from acetone is which type of reaction?
ChemistryAldehydes and KetonesJEE Main
Options:
  • A Electrophilic addition reaction
  • B Electrophilic substitution reaction
  • C Nucleophilic substitution reaction
  • D Nucleophilic addition reaction
Solution:
1713 Upvotes Verified Answer
The correct answer is: Nucleophilic addition reaction
Cyanohydrin formation:

This reaction is nucleophilic addition reaction.
Step (i): The nucleophilic carbon in the cyanide adds to the electrophilic carbon in the polar carbonyl group, electrons from the C=O move to the electronegative O creating an intermediate alkoxide.
Step (ii): An acid/base reaction protonation of the alkoxide oxygen creates the cyanohydrin product.

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