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Question: Answered & Verified by Expert
The functional group that shows negative resonance effect is:
ChemistryGeneral Organic ChemistryJEE MainJEE Main 2024 (01 Feb Shift 2)
Options:
  • A -NH2
  • B -OH
  • C -COOH
  • D -OR
Solution:
1602 Upvotes Verified Answer
The correct answer is: -COOH

The resonance effect definition can be given as a chemical phenomenon, observed in the characteristic compounds containing double bonds in the organic compounds. The organic compounds have these double bonds in the structures and have the overlapping of the p-orbitals, usually on the two adjacent sides of carbon atoms.

Negative Resonance Effect: The Negative resonance effect happens when the groups withdraw the electrons from the other molecules by the delocalisation process. Usually, the groups are denoted either by -R or -M. The molecular electron density is said to decrease in this process. The negative resonance effect examples are, C=O, -COOH, -CN and -NO2.

 

-COOH shows R effect, while rest 3 groups shows +R effect via lone pair.

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