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The half-life for radioactive decay of \({ }^{14} \mathrm{C}\) is 5730 years. An archaeological artifact containing wood had only \(80 \%\) of the \({ }^{14} \mathrm{C}\) found in a living tree. Estimate the age of the sample.
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Radioactive decay follows first order kinetics. Decay constant \((k)=\frac{0 \cdot 693}{t_{1 / 2}}=\frac{0.693}{5730}\) year \(^{-1}\)
\(\begin{aligned}
t &=\frac{2.303}{k} \log \frac{\left[\mathrm{A}_0\right]}{[\mathrm{A}]} \\
&=\frac{2.303}{\left(0.693 / 5730 \text { years }^{-1}\right)} \log \frac{100}{80} \\
&=\frac{2.303 \times 5730}{0.693} \times 0.0969=1845 \text { years. }
\end{aligned}\)
\(\begin{aligned}
t &=\frac{2.303}{k} \log \frac{\left[\mathrm{A}_0\right]}{[\mathrm{A}]} \\
&=\frac{2.303}{\left(0.693 / 5730 \text { years }^{-1}\right)} \log \frac{100}{80} \\
&=\frac{2.303 \times 5730}{0.693} \times 0.0969=1845 \text { years. }
\end{aligned}\)
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