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Question: Answered & Verified by Expert
The heat liberated when $1.89 \mathrm{~g}$ of benzoic acid is burnt in a bomb calorimeter at $25^{\circ} \mathrm{C}$ and it increases the temperature of $18.94 \mathrm{~kg}$ of water by $0.632^{\circ} \mathrm{C}$. If the specific heat of water at $25^{\circ} \mathrm{C}$ is $0.998 \mathrm{cal} / \mathrm{g}$ - $\mathrm{deg}$, the value of the heat of combustion of benzoic acid is
ChemistryThermodynamics (C)AIIMSAIIMS 2016
Options:
  • A $881.1 \mathrm{kcal}$
  • B $771.12 \mathrm{kcal}$
  • C $981.1 \mathrm{kcal}$
  • D $871.2 \mathrm{kcal}$
Solution:
1632 Upvotes Verified Answer
The correct answer is: $771.12 \mathrm{kcal}$
Given : Weight of benzoic acid $=1.89 \mathrm{~g}$;
Temperature of bomb calorimeter $=25^{\circ} \mathrm{C}=298 \mathrm{~K}$;
Mass of water $(m)=18.94 \mathrm{~kg}=18940 \mathrm{~g}$;
Increase in temperature $(\Delta t)=0.632^{\circ} \mathrm{C}$ and specific heat of water $(s)=0.998 \mathrm{cal} / \mathrm{g}$-deg.
We know that heat gained by water or heat liberated by benzoic acid $(Q)=m s \Delta t$
$=\frac{11946.14 \times 122}{1.89}=771126.5 \mathrm{cal}=771.12 \mathrm{kcal}$

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