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Question: Answered & Verified by Expert
The hybridization involved in complex NiCN42- is: (Atomic number of Ni = 28)
ChemistryCoordination CompoundsNEETNEET 2015 (Phase 2)
Options:
  • A dsp2
  • B sp3
  • C d2sp2
  • D d2sp3
Solution:
1783 Upvotes Verified Answer
The correct answer is: dsp2

NiCN42-

Oxidation state of Ni is +2

x-4=2

x=+2

Now, Ni2+=[Ar] 3d8 4s°

therefore, CN- is a strong field ligand. Hence, all unpaired electrons are paired up.

therefore, hybridisation of Ni(CN)42- is dsp2

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