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Question: Answered & Verified by Expert
The hyperconjugative stabilities of tertiary butyl carbocation and but-2−ene, respectively, are due to
ChemistryGeneral Organic ChemistryNEET
Options:
  • A σ p (empty) and σπ* electron delocalisations.
  • B σσ* and σπ electron delocalisations.
  • C σp (filled) and σπ electron delocalisations.
  • D p (filled) σ* and σπ* electron delocalisations.
Solution:
2166 Upvotes Verified Answer
The correct answer is: σ p (empty) and σπ* electron delocalisations.
Hyperconjugation involves delocalisation of σ electron of α C—H with π empty p-orbital. It increases stability of carbocation, free radical and alkenes by decreasing energy.

CH3-CH=CH2(σ-π* electron) delocalization

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