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Question: Answered & Verified by Expert
The incorrect statement regarding conformations of ethane is:
ChemistryGeneral Organic ChemistryJEE MainJEE Main 2024 (27 Jan Shift 2)
Options:
  • A Ethane has infinite number of conformations
  • B The dihedral angle in staggered conformation is 60°
  • C Eclipsed conformation is the most stable conformation.
  • D The conformations of ethane are interconvertible to one-another
Solution:
2580 Upvotes Verified Answer
The correct answer is: Eclipsed conformation is the most stable conformation.

In staggered conformation arrangement, the hydrogens of the two carbon atoms are staggered with respect to one another. As a result, they are at maximum distance apart and have minimum repulsion between the hydrogen atoms attached  to the two carbon atoms.

 In eclipsed conformation, the hydrogens of one carbon atom are directly behind those of the other. Consequently, the repulsion in between these hydrogen atoms is maximum. Therefore, staggered conformation of ethane is more stable than eclipsed conformation.

Eclipsed conformation is the least stable conformation of ethane.

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