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Question: Answered & Verified by Expert
The ionisation constant of NH4+ in water is 5.6 ×10-10 at 25 °C . The rate constant for the reaction of NH4+ and OH- to form NH3 and H2O at 25°C is 3.4×1010/mol-1S-1 . The rate constant for proton transfer from water to NH3 is
ChemistryChemical EquilibriumJEE Main
Options:
  • A 6.07×105
  • B 0.607×105
  • C 60.7×105
  • D 6.07×1010
Solution:
2759 Upvotes Verified Answer
The correct answer is: 6.07×105
NH4+NH3+H+;k1=5.6×1010 …(i)
H2OH++OH;k2=1×1014 …(ii)
K=k1k2=5.6×10-101×10-14
=5.6×104
By subtracting equation (ii) from equation (i) we get
NH4++OHNH3+H2O
From equation
kf=3.4×1010/mil-1S-1
NH3+H2ONH4++OH-
kr=?
K=kfkr
So kr=kfK=3.4×10105.6×104
=6.07×105

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