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Question: Answered & Verified by Expert
The lanthanide ion that would show colour is:
Chemistryd and f Block ElementsJEE MainJEE Main 2019 (08 Apr Shift 1)
Options:
  • A  Lu3+
  • B  La3+
  • C Gd3+
  • D Sm3+
Solution:
2616 Upvotes Verified Answer
The correct answer is: Sm3+

The elements or ions having unpaired electrons show colour. The valence shell electronic configuration of La3+ and Lu3+ are 4f0 and 4f14 respectively. Hence, they are colourless. Gd3+ is also colourless, this is because, here 4f orbitals are half filled,hence stable.As such f-f transitions are not possible because they will destroy the symmetry of 4f and make them unstable. Sm3+ has the valence shell electronic configuration 4f5, hence, it is coloured due to the presence of unpaired electrons.

La+3= Colourless
Gd+3= Colourless
Sm+3= Pale yellow colour
Lu+3= Colourless

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