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Question: Answered & Verified by Expert
The magnetic moment of $\mathrm{Ni}^{2+}$ ion (atomic number of $\mathrm{Ni}=28$ ) in BM unit is
ChemistryCoordination CompoundsJIPMERJIPMER 2019
Options:
  • A 1.73
  • B 4.81
  • C 5.96
  • D 2.84
Solution:
1961 Upvotes Verified Answer
The correct answer is: 2.84
$\mathrm{Ni}_{28}=[\mathrm{Ar}]_{18} 3 \mathrm{~d}^8 4 \mathrm{~s}^2, \mathrm{Ni}^{2+}=[\mathrm{Ar}]_{18} 3 \mathrm{~d}^8 4 \mathrm{~s}^2$

Number of unpaired electrons $=2$
Magnetic moment,
$\mu=\sqrt{n(n+2)}=\sqrt{2(2+2)}=\sqrt{8}=2.84 \mathrm{BM}$

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