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The \(\mathrm{F}^{-}\)ions make the enamel on teeth much harder by converting hydroxyapatite (the enamel on the surface of teeth) into much harder fluoroapatite having the formula.
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\(\left[3\left(\mathrm{Ca}_3\left(\mathrm{PO}_4\right)_2\right) \cdot \mathrm{CaF}_2\right]\)
Fluoroapatite $\Rightarrow\left[3 \mathrm{Ca}_3\left(\mathrm{PO}_4\right)_2 \cdot \mathrm{CaF}_2\right]$
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