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Question: Answered & Verified by Expert
The molar conductances of $\mathrm{NaCl}, \mathrm{HCl}$ and $\mathrm{CH}_3 \mathrm{COONa}$ at infinite dilution are $126.45,426.16$ and $91 \mathrm{ohm}^{-1} \mathrm{~cm}^2 \mathrm{~mol}^{-1}$ respectively. The molar conductance of $\mathrm{CH}_3 \mathrm{COOH}$ at infinite dilution is
ChemistryElectrochemistryJEE Main
Options:
  • A $201.28 \mathrm{ohm}^{-1} \mathrm{~cm}^2 \mathrm{~mol}^{-1}$
  • B $390.71 \mathrm{ohm}^{-1} \mathrm{~cm}^2 \mathrm{~mol}^{-1}$
  • C $698.28 \mathrm{ohm}^{-1} \mathrm{~cm}^2 \mathrm{~mol}^{-1}$
  • D $540.48 \mathrm{ohm}^{-1} \mathrm{~cm}^2 \mathrm{~mol}^{-1}$
Solution:
1730 Upvotes Verified Answer
The correct answer is: $390.71 \mathrm{ohm}^{-1} \mathrm{~cm}^2 \mathrm{~mol}^{-1}$
$\wedge_m^o\left(\mathrm{CH}_3 \mathrm{COOH}\right)=$
$\wedge^0\left(\mathrm{CH}_3 \mathrm{COONa}\right)+\wedge^{\circ}(\mathrm{HCl})-\wedge^{\circ}(\mathrm{NaCl})$
$=91+426.16-126.45=390.71 \mathrm{ohm}^{-1} \mathrm{~cm}^2 \mathrm{~mol}^{-1}$

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