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Question: Answered & Verified by Expert
The number of antibonding electron pairs in $\mathrm{O}_{2}^{2-}$ molecular ion on the basis of molecular orbital theory is
[Atomic number of $\mathrm{O}$ is 18 ]
ChemistryChemical Bonding and Molecular StructureCOMEDKCOMEDK 2020
Options:
  • A 2
  • B 3
  • C 4
  • D 5
Solution:
2308 Upvotes Verified Answer
The correct answer is: 4
Configuration of $\mathrm{O}_{2}^{2-}=\sigma 1 s^{2}, \sigma^{n} 1 s^{2}, \sigma 2 s^{2}, \sigma^{n} 2 s^{2}$, $\sigma 2 p_{x}^{2}, \pi 2 p_{x}^{2} \approx \pi 2 p_{y}^{2}, \pi^{4} 2 p_{x}^{2} \approx \pi \pi_{p}^{2}$.
$\therefore$ Number of antibonding electron pairs is four.

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