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Question: Answered & Verified by Expert
The number of tetrahedral and octahedral voids in CCP unit cell are respectively
ChemistrySolid StateTS EAMCETTS EAMCET 2017
Options:
  • A 4,8
  • B 8,4
  • C 12,6
  • D 6,12
Solution:
2311 Upvotes Verified Answer
The correct answer is: 8,4
In a closed packed structure [CCP or HCP] if there are $n$ spheres (atoms or ions) in packing; then;
Number of octahedral voids $=n$
Number of tetrahedral voids $=2 n$
In CCP;
Number of atoms $=4$
So number of octahedral voids $=4$
Number of tetrahedral voids $=8$

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