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Question: Answered & Verified by Expert
The number of unpaired electrons in
$\quad\left[\mathrm{NiCl}_{4}\right]^{2-}, \mathrm{Ni}(\mathrm{CO})_{4}$ and $\left[\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4}\right]^{2}$
respectively are
ChemistryCoordination CompoundsWBJEEWBJEE 2017
Options:
  • A 2,2,1
  • B 2,0,1
  • C 0,2,1
  • D 2,2,0
Solution:
2881 Upvotes Verified Answer
The correct answer is: 2,0,1
Configuration for metal (M) in various complex.


$\mathrm{Ni}^{2 *}$ has 2 unpaired electrons

$\mathrm{Ni}^{0}$ has zero unpaired electrons with
$s p^{3}$ -hybridisation.
$\mathrm{Cu}^{2}$ "has one unpaired electron with $d s p^{2}$ -hybridisation.

$\therefore$ (b) is the correct answer, i.e.
Number of unpaired electron (2,0,1)

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