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Question: Answered & Verified by Expert
The order of reactivity of phenol (I), nitrobenzene (II) and benzene (III) towards nitration is
ChemistryGeneral Organic ChemistryAP EAMCETAP EAMCET 2011
Options:
  • A (III) $>$ (I) $>$ (II)
  • B (II) $>$ (III) $>$ (I)
  • C (I) $>$ (III) $>$ (II)
  • D (I) $>$ (II) $>$ (III)
Solution:
1309 Upvotes Verified Answer
The correct answer is: (I) $>$ (III) $>$ (II)
Due to strong $+R$ effect of $-\mathrm{OH}$ group, the electron density in phenol (I) is much more than in benzene (III) while due to the strong $-R$ effect of the $-\mathrm{NO}_2$ group, the electron density in nitrobenzene (II) is much lower than in benzene. Hence, the order of reactivity towards nitration is as

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