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Question: Answered & Verified by Expert
The order of stability of aromatic hydrocarbons given below is

ChemistryGeneral Organic ChemistryTS EAMCETTS EAMCET 2019 (04 May Shift 2)
Options:
  • A $A < D < B < C$
  • B $D < A < B < C$
  • C $B < C < D < A$
  • D $A < D < B < C$
Solution:
1584 Upvotes Verified Answer
The correct answer is: $A < D < B < C$
Stability of benzene and polycyclic aromatic compounds is determined by resonance energy per ring. Benzene has resonance energy of $36 \mathrm{kcal} / \mathrm{mol}$ per ring, naphthalene has $30.3 \mathrm{kcal} / \mathrm{mol}$, phenanthrene has $30.5 \mathrm{kcal} / \mathrm{mol}$ and anthracene has $28 \mathrm{kcal} / \mathrm{mol}$ resonance energy per ring. Stability of aromatic compound is directly proportional to resonance energy per ring. Hence, order of stability : Benzene $(A)>$ phenanthrene $(D)>$ naphthalene $(B)>$ anthracene (C)
Thus, option (4) is correct.

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