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Question: Answered & Verified by Expert
The overlapping of orbitals in benzene is of the type
ChemistryChemical Bonding and Molecular StructureKCETKCET 2008
Options:
  • A sp-sp
  • B sp2-sp3
  • C $\mathrm{sp}^{2}-\mathrm{sp}^{2}$
  • D $\mathrm{sp}^{3}-\mathrm{sp}^{3}$
Solution:
1283 Upvotes Verified Answer
The correct answer is: $\mathrm{sp}^{2}-\mathrm{sp}^{2}$
The molecular orbital picture of benzene shows that in it all the six carbon atoms are $\mathrm{sp}^{2}$ hybridised. Out of these three ${s p^{2}}^{2}$ hybrid orbitals of each C atom, two orbitals overlap with $\mathrm{sp}^{2}$ hybrid orbitals of adjacent $C$ atoms to form six $\mathrm{C}-\mathrm{C}$ single bonds. The remaining $\mathrm{sp}^{2}$ orbital of each $C$ atom overlaps with -orbital of each hydrogen atom to form six $\mathrm{C}-\mathrm{H}$ single sigma bonds. Each C atom is now left with one unhybridised -orbital perpendicular to the plane of the ring.


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