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Question: Answered & Verified by Expert
The oxidation state and covalency of $\mathrm{Al}$ in $\left[\mathrm{AlCl}\left(\mathrm{H}_2 \mathrm{O}\right)_5\right]^{2+}$ are respectively
ChemistryCoordination CompoundsTS EAMCETTS EAMCET 2014
Options:
  • A $+6,6$
  • B $+3,6$
  • C $+2,6$
  • D $+3,3$
Solution:
1045 Upvotes Verified Answer
The correct answer is: $+3,6$
$$
\left[\mathrm{AlCl}\left(\mathrm{H}_2 \mathrm{O}\right)_5\right]^{2+}
$$
Let oxidation state of $\mathrm{Al}$ is $\mathrm{x}$.
$$
\begin{aligned}
& x+(-1)+5(0)=+2, \\
& x=+3
\end{aligned}
$$
Covalency of $\mathrm{Cl}=1$, covalency of $\mathrm{H}_2 \mathrm{O}=5$
$\therefore$ Total covalency $=1+5=6$

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