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The oxoacid of phosphorous which contains $4 \mathrm{P}-\mathrm{O}-\mathrm{H}$, $2 \mathrm{P}=\mathrm{O}$ and one $\mathrm{P}-\mathrm{O}-\mathrm{P}$ bond is
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Pyrophosphoric acid
The structure of pyrophosphoric acid is

No. of $\mathrm{P}-\mathrm{O}-\mathrm{H}$ bond $=4$
No. of $\mathrm{P}=\mathrm{O}$ bond $=2$
No. of $\mathrm{P}-\mathrm{O}-\mathrm{P}$ bond $=1$

No. of $\mathrm{P}-\mathrm{O}-\mathrm{H}$ bond $=4$
No. of $\mathrm{P}=\mathrm{O}$ bond $=2$
No. of $\mathrm{P}-\mathrm{O}-\mathrm{P}$ bond $=1$
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