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The pair from the following pairs having both compounds with net non-zero dipole moment is
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The dipole moment is the vector sum of all the bond moments. The and both have net non-zero dipole moment because the bond moments are not cancelled each other due to their tetrahedral structure. The -dichlorobenzene, trans-butene, benzene have zero dipole moment due to cancellation of bond moments. The -dichlorobenzene, cis-butene, anisidine has non-zero dipole moment.
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