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Question: Answered & Verified by Expert
The pair of metal ions that can give a spin only magnetic moment of 3.9BM for the complex [M(H2O)6]Cl2 , is:
ChemistryCoordination CompoundsJEE MainJEE Main 2019 (12 Jan Shift 1)
Options:
  • A Co2+ and Fe2+
  • B V2+ and Fe2+
  • C Cr2+ and Mn2+
  • D V2+ and Co2+
Solution:
2704 Upvotes Verified Answer
The correct answer is: V2+ and Co2+

If the complex is MH2O6Cl2, M will have +2 oxidation state and hence, it has already lost 2 electrons from s- orbital. Since it has μ=3.9 = n( n+2 ) n=3

3 unpaired so, the configuration can either be:

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